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Delivery Failed: Invalid Addresses

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I recently migrated from Outlook:
Zimbra Desktop Version: 7.2.5 GA
OS: Windows 8
Mail Type: POP

I cannot send any mails and get the above error message. The setup is corrected and has been validated.
I have had a look at similar problems in the forum but it hasnt helped.
It seems that the problems stems from the postfix_recipient_restriction.cf file but I cannot access it to make the suggested changes.
The search function does not find the file (hidden and sub-folders included in search), I have looked at all the files installed under c:\ProgramFilesx(86)\Zimbra\Zimbra Desktop\.... without success
I have also searched for the main.cf but hasnt been successfull

Veronica posted: Its because setting "reject_unverified_recipient" would make postfix send a verification notification to the recipient MTA server which recipient MTA needs to acknowledge. Many MTa don't do that causing mails to be deferred.

I am at a loss - how do I address the issue? How do I access this file?
Rgs Wynand

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